| The Mn(Salen)-catalyzed oxidative kinetic resolution of secondary alcohols: reaction development and scope | |
| Department | 羰基合成与选择氧化国家重点实验室 |
Chen QG(陈启干); Deng FG(邓凡果); Xia CG(夏春谷) ; Sun W(孙伟)
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| 2008 | |
| Source Publication | Tetrahedron: Asymmetry
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| ISSN | 0957-4166 |
| Volume | 19Pages:2359-2362 |
| Abstract | A series of chiral Mn(Salen) complexes have been synthesized and submitted to the kinetic resolution of secondary alcohols bearing a large hindrance in the biphasic system, which is composed of water and CH2Cl2. After evaluating the appropriate complex, additive, and other conditions, chiral secondary alcohols were obtained with enantiomeric excesses of up to 98.6% in 6 min. |
| Subject Area | 清洁催化与生物转化 |
| Funding Organization | the NSFC (20643008;20625308);the Chinese Academy of Sciences |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 清洁催化与生物转化研究组 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/1921 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Xia CG(夏春谷); Sun W(孙伟) |
| Recommended Citation GB/T 7714 | Chen QG,Deng FG,Xia CG,et al. The Mn(Salen)-catalyzed oxidative kinetic resolution of secondary alcohols: reaction development and scope[J]. Tetrahedron: Asymmetry,2008,19:2359-2362. |
| APA | 陈启干,邓凡果,夏春谷,&孙伟.(2008).The Mn(Salen)-catalyzed oxidative kinetic resolution of secondary alcohols: reaction development and scope.Tetrahedron: Asymmetry,19,2359-2362. |
| MLA | 陈启干,et al."The Mn(Salen)-catalyzed oxidative kinetic resolution of secondary alcohols: reaction development and scope".Tetrahedron: Asymmetry 19(2008):2359-2362. |
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| 34_Tetrahedron Asymm（181KB） | 开放获取 | License | View Application Full Text | |||
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