Fluorine and sulfur co-doped amorphous carbon films to achieve ultra-low friction under high vacuum | |
Department | 固体润滑国家重点实验室 |
Wang F(王福)1,2; Wang LP(王立平)1; Xue QJ(薛群基)1; Wang LP(王立平) | |
2016 | |
Source Publication | Carbon |
ISSN | 0008-6223 |
Volume | 96Pages:411-420 |
Abstract | Fluorine and sulfur co-doped amorphous carbon (a-C:S:F) films were synthesized from C2H2 and SF6 plasma mixture, and the bonding states of S and F in films were scrutinized. The a-C:S:F films exhibited a more ordered carbon structure than hydrogenated films. The friction behavior of films was tested against GCr15 bearing steel balls under high vacuum (HV) conditions. Ultra-low steady-state friction coefficient (0.01–0.02) was achieved for a-C:S:F films containing about 2.0 at.% H, depending on the concentrations of S and F in films. Graphite-like transfer layer on the ball surface provided a low-adhesive sliding surface terminated by –CF2- and –CF3 groups. The electrostatic repulsive interaction between the F-terminated transfer layer and the S- and F-terminated carbon structure was probably responsible for the ultra-low friction behavior. Intriguingly, the sp2-C clusters containing ‘thiophene-S’ (–C–S–C–) structure in films might contribute to the low friction when sliding against an highly fluorinated surface. These results demonstrate that the lubricating properties of a-C films in vacuum can be achieved through the S and F co-doping, which is of great significance for developing a-C films as vacuum lubricants. |
Subject Area | 材料科学与物理化学 |
DOI | 10.1016/j.carbon.2015.09.084 |
Funding Organization | the State Key Project of Fundamental Research of China (2013 CB 632302);the National Natural Science Foundation of China (Grant No. 51322508) |
Indexed By | SCI |
If | 6.337 |
Language | 英语 |
Funding Project | 低维材料摩擦学组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/19140 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Wang LP(王立平) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
Recommended Citation GB/T 7714 | Wang F,Wang LP,Xue QJ,et al. Fluorine and sulfur co-doped amorphous carbon films to achieve ultra-low friction under high vacuum[J]. Carbon,2016,96:411-420. |
APA | Wang F,Wang LP,Xue QJ,&王立平.(2016).Fluorine and sulfur co-doped amorphous carbon films to achieve ultra-low friction under high vacuum.Carbon,96,411-420. |
MLA | Wang F,et al."Fluorine and sulfur co-doped amorphous carbon films to achieve ultra-low friction under high vacuum".Carbon 96(2016):411-420. |
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1-s2.0-S000862231530(3513KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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