Tailoring the properties of palygorskite by various organic acids via a one-pot hydrothermal process: A comparative study for removal of toxic dyes | |
Department | 环境材料与生态化学研究发展中心 |
Zhang ZF(张志芳)1,2; Wang WB(王文波)1,3; Kang YR(康玉茹)1,3; Zong L(宗莉)1,3; Wang AQ(王爱勤)1,3; Wang AQ(王爱勤); Wang WB(王文波) | |
2016 | |
Source Publication | Applied Clay Science |
ISSN | 0169-1317 |
Volume | 120Pages:28-39 |
Abstract | Naturally abundant palygorskite (PAL) has been frequently used as an efficient, stable, low cost and environment-benign adsorbent to remove toxic pollutants for alleviating their harm to human health. However, the adsorption capacity of natural PAL is limited, which restricts its applications as an efficient adsorbent. As the aim to improve the adsorption capability of natural PAL and develop a high-efficient silicate adsorbent, the organic acids with different structures (i.e., acetic acid, glycolic acid, glycine, chloroacetic acid, benzoic acid, oxalic acid and citric acid) were employed to modify natural PAL via a simple one-step hydrothermal process. The effect of hydrothermal process in the presence of organic acids on the microscopic structure, physico-chemical features and adsorption properties of the PAL-derived adsorbent was studied comparatively using the dyes methylene blue (MB), methyl violet (MV) and malachite green (MG) as the model pollutants. It was found that the structural evolution of PAL and the introduction of functional groups positively contribute to improve the adsorption capacity. The PAL-derived adsorbents in the presence of chloroacetic acid (CAA-PAL) and citric acid (CA-PAL) show excellent adsorption capacity, which could almost completely remove the MB, MV and MG dyes from 200 mg/L of the solution, but the raw PAL can only remove 59% (for MB), 63% (for MV) and 88% (for MG). The intensified electrostatic attraction, hydrogen-bonding interaction and chemical association of –Si–O− groups with dyes, resulting from the hydrothermal evolution of PAL crystal, are primarily responsible for the enhancement of adsorption capacity. |
Keyword | Palygorskite Hydrothermal Process Organic Acids Dye Removal Adsorption |
Subject Area | 环境材料与生态化学 ; 材料学 |
DOI | 10.1016/j.clay.2015.11.019 |
Funding Organization | the National Natural Science Foundation of China (No. 51403221);the “863” Project of the Ministry of Science and Technology, China (No. 2013AA032003);the National Science Foundation of Gansu province (No. 1208RJYA087) |
Indexed By | SCI |
If | 3.101 |
Language | 英语 |
Funding Project | 功能复合材料组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/19095 |
Collection | 环境材料与生态化学研究发展中心 |
Corresponding Author | Wang AQ(王爱勤); Wang WB(王文波) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Ecomat & Green Chem, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, R&D Ctr Xuyi Palygorskite Appl Technol, Xuyi 211700, Peoples R China |
Recommended Citation GB/T 7714 | Zhang ZF,Wang WB,Kang YR,et al. Tailoring the properties of palygorskite by various organic acids via a one-pot hydrothermal process: A comparative study for removal of toxic dyes[J]. Applied Clay Science,2016,120:28-39. |
APA | Zhang ZF.,Wang WB.,Kang YR.,Zong L.,Wang AQ.,...&王文波.(2016).Tailoring the properties of palygorskite by various organic acids via a one-pot hydrothermal process: A comparative study for removal of toxic dyes.Applied Clay Science,120,28-39. |
MLA | Zhang ZF,et al."Tailoring the properties of palygorskite by various organic acids via a one-pot hydrothermal process: A comparative study for removal of toxic dyes".Applied Clay Science 120(2016):28-39. |
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