Novel route for the synthesis of 8-oxa-3-azabicyclo[3.2.1]octane: One-pot aminocyclization of 2,5-tetrahydrofurandimethanol catalyzed by Pt/NiCuAlOx

doi:10.1016/j.catcom.2014.09.027

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	Novel route for the synthesis of 8-oxa-3-azabicyclo[3.2.1]octane: One-pot aminocyclization of 2,5-tetrahydrofurandimethanol catalyzed by Pt/NiCuAlOx
Department	绿色化学研究发展中心
	Cui XJ(崔新江)1 ; Yuan HK(袁航空)1 ; Jerry-Peng Li 2; Floryan De Campo 2; Marc Pera-Titus 2; Deng YQ(邓友全)1 ; Shi F(石峰)1 ; Shi F(石峰)
The second department	osso国家重点实验室
	2015
Source Publication	Catalysis Communications
ISSN	1566-7367
Volume	58 Issue:5 Pages:195-199
Abstract	2,5-Tetrahydrofurandimethanol (THFDM) was selectively transformed into 8-oxa-3-azabicyclo[3.2.1] octane (OABCO), a valuable building block for the synthesis of bioactive molecules, via one-pot aminocyclization with ammonia catalyzed by Pt/NiCuAlO_x. Under optimized conditions (200 ℃, 6–16 h, 0.5 MPa hydrogen, 0.4 MPa ammonia), the OABCO yield reached 58% with 100% THFDM conversion.
Keyword	Tetrahydrofurandimethanol 8-oxa-3-azabicyclo[3.2.1]Octane Ammonia Amination Biomass
Subject Area	物理化学与绿色催化
DOI	10.1016/j.catcom.2014.09.027
Indexed By	SCI
If	3.699
Language	英语
Funding Project	纳米催化课题组;绿色催化课题组
compositor	第一作者单位
Citation statistics	Cited Times:3[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.licp.cn/handle/362003/19037
Collection	绿色化学研究发展中心羰基合成与选择氧化国家重点实验室（OSSO）
Corresponding Author	Shi F(石峰)
Affiliation	1.Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences 2.Eco-Efficient Products and Processes Laboratory (E2P2L), UMI 3464 CNRS—Solvay
Recommended Citation GB/T 7714	Cui XJ,Yuan HK,Jerry-Peng Li,et al. Novel route for the synthesis of 8-oxa-3-azabicyclo[3.2.1]octane: One-pot aminocyclization of 2,5-tetrahydrofurandimethanol catalyzed by Pt/NiCuAlOx[J]. Catalysis Communications,2015,58(5):195-199.
APA	Cui XJ.,Yuan HK.,Jerry-Peng Li.,Floryan De Campo.,Marc Pera-Titus.,...&石峰.(2015).Novel route for the synthesis of 8-oxa-3-azabicyclo[3.2.1]octane: One-pot aminocyclization of 2,5-tetrahydrofurandimethanol catalyzed by Pt/NiCuAlOx.Catalysis Communications,58(5),195-199.
MLA	Cui XJ,et al."Novel route for the synthesis of 8-oxa-3-azabicyclo[3.2.1]octane: One-pot aminocyclization of 2,5-tetrahydrofurandimethanol catalyzed by Pt/NiCuAlOx".Catalysis Communications 58.5(2015):195-199.

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