Reduced Graphene Oxide/Marcasite-Type Cobalt Selenide Nanocrystals as an Anode for Lithium-Ion Batteries with Excellent Cyclic Performance | |
Department | 固体润滑国家重点实验室 |
Li ZP(李章朋)1,2; Xue HT(薛宏涛)2; Wang JQ(王金清)1; Tang YB(唐永炳)2; Lee, Chun-Sing2; Yang SR(杨生荣)1; Wang JQ(王金清) | |
2015 | |
Source Publication | ChemElectroChem |
ISSN | 2196-0216 |
Volume | 2Issue:11Pages:1682-1686 |
Abstract | We report a graphene/cobalt selenide (rGO/CoSe2) composite as an anode material for lithium-ion batteries. The prepared composite shows a wrinkled morphology with the CoSe2 nanoparticles tightly anchored/wrapped on/in the rGO sheets. The rGO/CoSe2 composite exhibits enhanced electrochemical performance with higher capacity, better rate capability, and cycling performance compared to pure CoSe2. The rGO/CoSe2 composite delivers a high initial reversible capacity of 726 mAhg-1 and a very high capacity of 1577 mAhg-1 after 200 cycles at a current density of 200 mAg-1 (0.38C). The rGO sheets in the composite play important roles for the improvement in electrochemical properties, for example, the rGO sheet not only enhances the electrical conductivity of the whole electrode, but also alleviates the structure degradation caused by volume expansion of CoSe2 during discharge/charge processes, resulting in improved lithium-storage performances. |
Keyword | Anode Materials Cobalt Selenide Composites Graphene Lithium-ion Batteries |
Subject Area | 材料科学与物理化学 |
DOI | 10.1002/celc.201500179 |
Funding Organization | the National Natural Science Foundation of China (Grant Nos. 51075384;51205385) |
Indexed By | SCI |
If | 3.506 |
Language | 英语 |
Funding Project | 聚合物摩擦学组 |
compositor | 第一作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/18876 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Lee, Chun-Sing; Wang JQ(王金清) |
Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 2.City Univ Hong Kong, Dept Phys & Mat Sci, Ctr Super Diamond & Adv Films COSDAF, Kowloon, Hong Kong, Peoples R China |
Recommended Citation GB/T 7714 | Li ZP,Xue HT,Wang JQ,et al. Reduced Graphene Oxide/Marcasite-Type Cobalt Selenide Nanocrystals as an Anode for Lithium-Ion Batteries with Excellent Cyclic Performance[J]. ChemElectroChem,2015,2(11):1682-1686. |
APA | Li ZP.,Xue HT.,Wang JQ.,Tang YB.,Lee, Chun-Sing.,...&王金清.(2015).Reduced Graphene Oxide/Marcasite-Type Cobalt Selenide Nanocrystals as an Anode for Lithium-Ion Batteries with Excellent Cyclic Performance.ChemElectroChem,2(11),1682-1686. |
MLA | Li ZP,et al."Reduced Graphene Oxide/Marcasite-Type Cobalt Selenide Nanocrystals as an Anode for Lithium-Ion Batteries with Excellent Cyclic Performance".ChemElectroChem 2.11(2015):1682-1686. |
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12 LZP.pdf(1171KB) | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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