| Efficient synthesis of diphenyl carbonate from dibutyl carbonate and phenol using square-shaped Zn-Ti-O nanoplates as solid acid catalysts | |
| Department | 绿色化学研究发展中心 |
Wang PX(王培学)1,2 ; Liu SM(刘士民)1; Zhou F(周锋)1,2; Yang BQ(杨本群)1,2; Alshammari, Ahmad S.3; Deng YQ(邓友全)1; Deng YQ(邓友全)
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| The second department | 固体润滑国家重点实验室 |
| 2015 | |
| Source Publication | RSC Advances
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| ISSN | 2046-2069 |
| Volume | 5Issue:103Pages:84621-84626 |
| Abstract | Square-shaped Zn/Ti oxides were prepared by a co-precipitation method and used for the synthesis of diphenyl carbonate (DPC) via transesterification of dibutyl carbonate (DBC) with phenol. The results showed that a 51% yield of butyl phenyl carbonate (BPC) and 13% yield of DPC could be achieved at 205 degrees C in the presence of 3ZnTi-400 (Zn : Ti molar ratio 3 : 1). Moreover, it is found that 3ZnTi-400 was also an active catalyst for the disproportionation of BPC to DPC, and 80% conversion of BPC was obtained at 190 degrees C. The prepared catalysts could be reused for three runs of the transesterification without noticeable deactivation. The catalysts were characterized by XRD, SEM, XPS, and TPD with the aim of establishing the relationship between catalytic performance and structure. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c5ra17655g |
| Indexed By | SCI |
| If | 3.289 |
| Language | 英语 |
| Funding Project | 绿色催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/18756 |
| Collection | 绿色化学研究发展中心 固体润滑国家重点实验室（LSL） |
| Corresponding Author | Deng YQ(邓友全) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Ctr Green Chem & Catalysis, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China 3.King Abdulaziz City Sci & Technol, Natl Nanotechnol Res Ctr, Riyadh 11442, Saudi Arabia |
| Recommended Citation GB/T 7714 | Wang PX,Liu SM,Zhou F,et al. Efficient synthesis of diphenyl carbonate from dibutyl carbonate and phenol using square-shaped Zn-Ti-O nanoplates as solid acid catalysts[J]. RSC Advances,2015,5(103):84621-84626. |
| APA | Wang PX.,Liu SM.,Zhou F.,Yang BQ.,Alshammari, Ahmad S..,...&邓友全.(2015).Efficient synthesis of diphenyl carbonate from dibutyl carbonate and phenol using square-shaped Zn-Ti-O nanoplates as solid acid catalysts.RSC Advances,5(103),84621-84626. |
| MLA | Wang PX,et al."Efficient synthesis of diphenyl carbonate from dibutyl carbonate and phenol using square-shaped Zn-Ti-O nanoplates as solid acid catalysts".RSC Advances 5.103(2015):84621-84626. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| c5ra17655g.pdf（563KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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