| Mesoporous Mn-Zr composite oxides with a crystalline wall: synthesis, characterization and application | |
| Department | OSSO国家重点实验室 |
Miao ZC(苗智超)1,2 ; Zhao HH(赵华华)1; Yang J(杨建)1; Zhao J(赵军)1; Song HL(宋焕玲)1,3; Chou LJ(丑凌军)1,3; Chou LJ(丑凌军)
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| 2015 | |
| Source Publication | Dalton Transactions
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| ISSN | 1477-9226 |
| Volume | 44Issue:7Pages:2997-3001 |
| Abstract | Mesoporous Mn-Zr composite oxides (M-MnZr) with a crystalline wall were designed and achieved by a facile one-pot evaporation-induced self-assembly (EISA) strategy. As proved by XRD, HRTEM and SAED characterization, the wall of the obtained mesoporous materials exhibited a typical tetragonal phase of ZrO2. In addition, the introduced manganese species were homogeneously dispersed in the mesoporous skeleton. N2-physisorption and TEM results showed that all the final materials possessed an obvious mesoporous structure accompanied by a large specific surface area (similar to 120 m2 g-1), big pore volume (similar to 0.2 cm3 g-1) and uniform pore size (similar to 4.9 nm). In addition, the liquid phase oxidation was chosen as the test reaction and the excellent catalytic performance of M-MnZr demonstrated their potential applications in oxidation reactions. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c4dt03835e |
| Funding Organization | the "Strategic Priority Research Program" of the Chinese Academy of Sciences, Grant no. XDA09030101;the National Natural Science Foundation of China (no. 21133011;21373244) |
| Indexed By | SCI |
| If | 4.177 |
| Language | 英语 |
| Funding Project | 多相选择氧化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/18683 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Chou LJ(丑凌军) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 3.Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion, Suzhou 215123, Peoples R China |
| Recommended Citation GB/T 7714 | Miao ZC,Zhao HH,Yang J,et al. Mesoporous Mn-Zr composite oxides with a crystalline wall: synthesis, characterization and application[J]. Dalton Transactions,2015,44(7):2997-3001. |
| APA | Miao ZC.,Zhao HH.,Yang J.,Zhao J.,Song HL.,...&丑凌军.(2015).Mesoporous Mn-Zr composite oxides with a crystalline wall: synthesis, characterization and application.Dalton Transactions,44(7),2997-3001. |
| MLA | Miao ZC,et al."Mesoporous Mn-Zr composite oxides with a crystalline wall: synthesis, characterization and application".Dalton Transactions 44.7(2015):2997-3001. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Miao-2015-Mesoporous（2121KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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