| Palladium-N-heterocyclic carbene (NHC)-catalyzed synthesis of 2-ynamides via oxidative aminocarbonylation of alkynes with amines | |
| Department | OSSO国家重点实验室 |
Zhang CY(张春艳)1,2 ; Liu JH(刘建华)1; Xia CG(夏春谷)1; Liu JH(刘建华); Xia CG(夏春谷)
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| 2015 | |
| Source Publication | Catalysis Science and Technology
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| ISSN | 2044-4753 |
| Volume | 5Issue:10Pages:4750-4754 |
| Abstract | A series of palladium-NHC complexes was prepared and their catalytic activity in the oxidative aminocarbonylation of alkynes with amines has been developed using oxygen as the benign oxidant, leading to an efficient approach toward the formation of a wide range of 2-ynamides with high atom efficiency. Utilizing the distinctive reactivity of this palladium-NHC catalysis, both the aryl and the alkyl of the alkynes could be efficiently incorporated into the 2-ynamide. Mechanistic studies provide some evidence to support that amido-Pd could be transformed into amido-Pd-alkynyl. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c5cy00993f |
| Funding Organization | the National Natural Science Foundation of China (no. 21373248;21133011) |
| Indexed By | SCI |
| If | 5.287 |
| Language | 英语 |
| Funding Project | 均相催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/18667 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Liu JH(刘建华); Xia CG(夏春谷) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China |
| Recommended Citation GB/T 7714 | Zhang CY,Liu JH,Xia CG,et al. Palladium-N-heterocyclic carbene (NHC)-catalyzed synthesis of 2-ynamides via oxidative aminocarbonylation of alkynes with amines[J]. Catalysis Science and Technology,2015,5(10):4750-4754. |
| APA | Zhang CY,Liu JH,Xia CG,刘建华,&夏春谷.(2015).Palladium-N-heterocyclic carbene (NHC)-catalyzed synthesis of 2-ynamides via oxidative aminocarbonylation of alkynes with amines.Catalysis Science and Technology,5(10),4750-4754. |
| MLA | Zhang CY,et al."Palladium-N-heterocyclic carbene (NHC)-catalyzed synthesis of 2-ynamides via oxidative aminocarbonylation of alkynes with amines".Catalysis Science and Technology 5.10(2015):4750-4754. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| c5cy00993f.pdf（1630KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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