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Efficient photocatalytic water oxidation catalyzed by polyoxometalate [Fe11(H2O)14(OH)2(W3O10)2(α-SbW9O33)6]27− based on abundant metals
DepartmentOSSO国家重点实验室
Du, Xiaoqiang1; Ding Y(丁勇)1,2; Song, Fangyuan1; Ma, Baochun1; Zhao, Junwei3; Song, Jie4
2015
Source PublicationChemical Communications
ISSN1359-7345
Volume51Issue:73Pages:13925-13928
Abstract

An eleven iron-containing nanoscale inorganic polyanionic oxide cluster was reported as the first example for exceptional photocatalytic water oxidation. Under optimal conditions, a remarkable turn-over number (TON) of 1815 ± 50 and a turn-over frequency (TOFinitial) of 6.3 s−1 over 1 were achieved for water oxidation.

Subject Area物理化学与绿色催化
DOI10.1039/c5cc04551g
Funding Organizationthe National Natural Science Foundation of China (Grant No. 21173105;21172098)
Indexed BySCI
If6.567
Language英语
compositor第二作者单位
Citation statistics
Cited Times:87[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/18584
Collection羰基合成与选择氧化国家重点实验室(OSSO)
Affiliation1.State Key Laboratory of Applied Organic Chemistry, Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province, and College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China
2.State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China
3.Henan Key Laboratory of Polyoxometalate Chemistry, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, P. R. China
4.Department of Biomedical Engineering, Emory University and Georgia Institute of Technology, Atlanta, USA
Recommended Citation
GB/T 7714
Du, Xiaoqiang,Ding Y,Song, Fangyuan,et al. Efficient photocatalytic water oxidation catalyzed by polyoxometalate [Fe11(H2O)14(OH)2(W3O10)2(α-SbW9O33)6]27− based on abundant metals[J]. Chemical Communications,2015,51(73):13925-13928.
APA Du, Xiaoqiang,Ding Y,Song, Fangyuan,Ma, Baochun,Zhao, Junwei,&Song, Jie.(2015).Efficient photocatalytic water oxidation catalyzed by polyoxometalate [Fe11(H2O)14(OH)2(W3O10)2(α-SbW9O33)6]27− based on abundant metals.Chemical Communications,51(73),13925-13928.
MLA Du, Xiaoqiang,et al."Efficient photocatalytic water oxidation catalyzed by polyoxometalate [Fe11(H2O)14(OH)2(W3O10)2(α-SbW9O33)6]27− based on abundant metals".Chemical Communications 51.73(2015):13925-13928.
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