Solution combustion synthesis and enhanced electrochemical performance Li1.2Ni0.2Mn0.6O2 nanoparticles by controlling NO3-/CH3COO- ratio of the precursors
Department先进润滑与防护材料研究发展中心
Zhang, Qingtang1; Mei, Juntao1; Xie, Xiaolong1; Wang, Xiaomei1; Zhang JY(张俊彦)2
The second department固体润滑国家重点实验室
2015
Source PublicationMaterials Research Bulletin
ISSN0025-5408
Volume70Pages:397-402
AbstractLithium-rich layer oxide Li1.2Ni0.2Mn0.6O2 nanoparticles were fabricated through solution combustion synthesis by controlling NO3/CH3COO ratio of the precursors. The relationships between the NO3/CH3COO ratio and structure as well as electrochemical performance of Li1.2Ni0.2Mn0.6O2 nanoparticles are investigated. XRD reveals that Li1.2Ni0.2Mn0.6O2 nanoparticles obtained with a suitable NO3/CH3COO ratio of 3:1 (LLO-3N1A) is composed of the smallest nanocrystallite of 18 nm. SEM reflects that the average primary particles of LLO-3N1A are the smallest with a size of 35 nm. Those unique characteristic guarantee the excellent electrochemical performance of LLO-3N1A. LLO-3N1A exhibits a specific capacity of 252.3 mA h g−1 at 0.1 C. In addition, LLO-3N1A also shows best rate capability among the four prepared Li1.2Ni0.2Mn0.6O2 samples.
KeywordLayered Compounds Sol-gel Chemistry Electrochemical Measurements Electrochemical Properties Energy Storage
Subject Area材料科学与物理化学
DOI10.1016/j.materresbull.2015.05.005
Funding Organizationthe Open Fund of State Key Laboratory of Advanced Processing and Recycling of Non-ferrous Metals (SKL1306);the National Nature Science Foundation of China (No. 21466020)
Indexed BySCI
If2.288
Language英语
compositor第二作者单位
Citation statistics
Cited Times:10[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/18572
Collection中国科学院材料磨损与防护重点实验室/先进润滑与防护材料研究发展中心
固体润滑国家重点实验室(LSL)
Corresponding AuthorZhang, Qingtang; Wang, Xiaomei
Affiliation1.Lanzhou Univ Technol, Sch Petrochem Engn, State Key Lab Adv Proc & Recycling Nonferrous Met, Lanzhou 730050, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Zhang, Qingtang,Mei, Juntao,Xie, Xiaolong,et al. Solution combustion synthesis and enhanced electrochemical performance Li1.2Ni0.2Mn0.6O2 nanoparticles by controlling NO3-/CH3COO- ratio of the precursors[J]. Materials Research Bulletin,2015,70:397-402.
APA Zhang, Qingtang,Mei, Juntao,Xie, Xiaolong,Wang, Xiaomei,&Zhang JY.(2015).Solution combustion synthesis and enhanced electrochemical performance Li1.2Ni0.2Mn0.6O2 nanoparticles by controlling NO3-/CH3COO- ratio of the precursors.Materials Research Bulletin,70,397-402.
MLA Zhang, Qingtang,et al."Solution combustion synthesis and enhanced electrochemical performance Li1.2Ni0.2Mn0.6O2 nanoparticles by controlling NO3-/CH3COO- ratio of the precursors".Materials Research Bulletin 70(2015):397-402.
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