| A conjugated ketone as a catalyst in alcohol amination reactions under transition-metal and hetero-atom free conditions | |
| Department | 绿色化学研究发展中心 |
Dai XC(代兴超); Cui XJ(崔新江) ; Deng YQ(邓友全); Shi F(石峰); Shi F(石峰)
| |
| The second department | osso国家重点实验室 |
| 2015 | |
| Source Publication | RSC Advances
 |
| ISSN | 2046-2069 |
| Volume | 5Issue:54Pages:43589-43593 |
| Abstract | Here, we show the results of a molecular-defined conjugated ketone catalyzed alcohol amination reaction. Under the optimized reaction conditions, the yields to the desired products reached 98%. The reaction mechanism and kinetic study supposed that carbonyl-hydroxyl groups are the catalytically active sites, and the transfer-hydrogenation reactions progress via the recycling of carbonyl and hydroxyl groups. The catalytic process shows promise as an efficient and economic route for alcohol amination reactions. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c5ra07681a |
| Indexed By | SCI |
| If | 3.840 |
| Language | 英语 |
| Funding Project | 纳米催化课题组;绿色催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/18453 |
| Collection | 绿色化学研究发展中心 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Shi F(石峰) |
| Affiliation | Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Ctr Green Chem & Catalysis, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Dai XC,Cui XJ,Deng YQ,et al. A conjugated ketone as a catalyst in alcohol amination reactions under transition-metal and hetero-atom free conditions[J]. RSC Advances,2015,5(54):43589-43593. |
| APA | Dai XC,Cui XJ,Deng YQ,Shi F,&石峰.(2015).A conjugated ketone as a catalyst in alcohol amination reactions under transition-metal and hetero-atom free conditions.RSC Advances,5(54),43589-43593. |
| MLA | Dai XC,et al."A conjugated ketone as a catalyst in alcohol amination reactions under transition-metal and hetero-atom free conditions".RSC Advances 5.54(2015):43589-43593. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| c5ra07681a.pdf（380KB） | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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