| Hierarchically structured SAPO-5 molecular sieve catalysts with tailored mesoporosity for alkylation reaction | |
| Department | OSSO国家重点实验室 |
Zhao XH(赵新红)1; Wen, Juanjuan1; Zhao, Jiangbo1; Li A(李安)1; Li GX(李贵贤)1; Wang XL(王晓来)2 ; Zhao XH(赵新红)
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| 2015 | |
| Source Publication | Journal of Porous Materials
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| ISSN | 1380-2224 |
| Volume | 22Issue:3Pages:577-584 |
| Abstract | Hierarchically structured SAPO-5 molecular sieve was synthesized by microwave-assisted ionothermal method in eutectic mixture solvent. Their porous texture and acid properties were characterized by nitrogen physisorption, SEM, TEM and NH3-TPD. The results show that the mesoporous volume of SAPO-5 can be tuned via simply varying the degree of supersaturation, the type of mineralizer or replacing partly succinic acid with sebacic acid. A lower degree of supersaturation and using ammonium fluoride as a mineralizer favor the synthesis of SAPO-5 with large mesoporous volume. Notably, the introduction of sebacic acid can lead to three-level micro-meso-macroporous structure (sample C1). Five typical samples were selected as catalysts and tested in the alkylation of benzene with benzyl alcohol. Among all catalysts, the sample C1, whose aspect ratio is the lowest, exhibited the best catalytic activity, giving a 91 % benzyl alcohol conversion. The diffraction peak intensity ratio of I002/I100 was proposed to be a good indicator in fabricating a highly active SAPO-5 catalyst for this reaction. |
| Keyword | Sapo-5 Molecular Sieve Microwave Eutectic Mixture Hierarchical Alkylation Reaction |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1007/s10934-015-9929-5 |
| Funding Organization | the National Nat¬ural Science Foundation of China (Grant Nos. 21306072;51263012);Development Program of Lanzhou University of Technology for excellent teachers (Grant No. Q201113) |
| Indexed By | SCI |
| If | 1.385 |
| Language | 英语 |
| Funding Project | 多相选择氧化课题组 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/18434 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Zhao XH(赵新红) |
| Affiliation | 1.Lanzhou Univ Technol, Sch Petrochem Engn, Lanzhou 730050, Peoples R China 2.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Zhao XH,Wen, Juanjuan,Zhao, Jiangbo,et al. Hierarchically structured SAPO-5 molecular sieve catalysts with tailored mesoporosity for alkylation reaction[J]. Journal of Porous Materials,2015,22(3):577-584. |
| APA | Zhao XH.,Wen, Juanjuan.,Zhao, Jiangbo.,Li A.,Li GX.,...&赵新红.(2015).Hierarchically structured SAPO-5 molecular sieve catalysts with tailored mesoporosity for alkylation reaction.Journal of Porous Materials,22(3),577-584. |
| MLA | Zhao XH,et al."Hierarchically structured SAPO-5 molecular sieve catalysts with tailored mesoporosity for alkylation reaction".Journal of Porous Materials 22.3(2015):577-584. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 2015577-584.pdf（1276KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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