| Carbon-catalysed reductive hydrogen atom transfer reactions | |
| Department | 绿色化学研究发展中心 |
Yang HM(杨慧敏)1,2 ; Cui XJ(崔新江)1; Dai XC(代兴超)1,2; Deng YQ(邓友全)1; Shi F(石峰)1; Shi F(石峰)
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| The second department | osso国家重点实验室 |
| 2015 | |
| Source Publication | Nature Communications
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| ISSN | 2041-1723 |
| Volume | 6 |
| Abstract | Generally, transition metal catalysts are essential for the reductive hydrogen atom transfer reaction, which is also known as the transfer hydrogenation reaction or the borrowing-hydrogen reaction. It has been reported that graphene can be an active catalyst in ethylene and nitrobenzene reductions, but no report has described carbon-based materials as catalysts for alcohol amination via the borrowing-hydrogen reaction mechanism. Here we show the results from the preparation, characterization and catalytic performance investigation of carbon catalysts in transition metal-free borrowing-hydrogen reactions using alcohol amination and nitro compound/ketone reduction as model reactions. XPS, XRD, SEM, FT-IR and N2 adsorption–desorption studies revealed that C=O group in the carbon catalysts may be a possible catalytically active site, and high surface area is important for gaining high activity. The activity of the carbon catalyst remained unchanged after reuse. This study provides an attractive and useful methodology for a wider range of applications. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1038/ncomms7478 |
| Indexed By | SCI |
| If | 11.470 |
| Language | 英语 |
| Funding Project | 纳米催化课题组;绿色催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/18430 |
| Collection | 绿色化学研究发展中心 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Shi F(石峰) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Ctr Green Chem & Catalysis, Lanzhou 730000, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Yang HM,Cui XJ,Dai XC,et al. Carbon-catalysed reductive hydrogen atom transfer reactions[J]. Nature Communications,2015,6. |
| APA | Yang HM,Cui XJ,Dai XC,Deng YQ,Shi F,&石峰.(2015).Carbon-catalysed reductive hydrogen atom transfer reactions.Nature Communications,6. |
| MLA | Yang HM,et al."Carbon-catalysed reductive hydrogen atom transfer reactions".Nature Communications 6(2015). |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 31.pdf（1642KB） | 期刊论文 | 出版稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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