| Light-Sensitive and Recoverable N-Heterocyclic Carbene Copper(I) Complex in Homogeneous Catalysis | |
| Department | OSSO国家重点实验室 |
Zhang GD(张国栋)1,2; Lang R(郎睿)1,2 ; Wang WL(汪文龙)1; Lv H(吕辉)1; Zhao LY(赵丽源)1; Xia CG(夏春谷)1; Li FW(李福伟)1; Li FW(李福伟)
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| 2015 | |
| Source Publication | Advanced Synthesis and Catalysis
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| ISSN | 1615-4150 |
| Volume | 357Issue:5Pages:917-922 |
| Abstract | The synthesis of a light-responsive N-heterocyclic carbene copper(I) complex by introducing a nitrobenzospiropyran unit into the carbene ligand was developed. The solubility of this complex was controlled through reversible conversion between its netural and ionic states using ultraviolet light irradiation. Taking advantage of such a light-sensitive property facilitated its recovery and reuse in copper(I)-catalyzed homogeneous oxidation and "click" reactions. |
| Keyword | Carbenes Copper Homogeneous Catalysis Ligand Design Sustainable Chemistry |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/adsc.201401140 |
| Funding Organization | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21133011;21373246;21403258) |
| Indexed By | SCI |
| If | 5.663 |
| Language | 英语 |
| Funding Project | 均相催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/18389 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Li FW(李福伟) |
| Affiliation | 1.Chinese Acad Sci, Lanzhou Inst Chem Phys, Suzhou Res Inst, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Grad Univ, Beijing 100049, Peoples R China |
| Recommended Citation GB/T 7714 | Zhang GD,Lang R,Wang WL,et al. Light-Sensitive and Recoverable N-Heterocyclic Carbene Copper(I) Complex in Homogeneous Catalysis[J]. Advanced Synthesis and Catalysis,2015,357(5):917-922. |
| APA | Zhang GD.,Lang R.,Wang WL.,Lv H.,Zhao LY.,...&李福伟.(2015).Light-Sensitive and Recoverable N-Heterocyclic Carbene Copper(I) Complex in Homogeneous Catalysis.Advanced Synthesis and Catalysis,357(5),917-922. |
| MLA | Zhang GD,et al."Light-Sensitive and Recoverable N-Heterocyclic Carbene Copper(I) Complex in Homogeneous Catalysis".Advanced Synthesis and Catalysis 357.5(2015):917-922. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 917_ftp.pdf（831KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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