| Copper-catalyzed radical cascade cyclization for the synthesis of phosphorated indolines | |
| Department | OSSO国家重点实验室 |
| Zhang HY(张宏宇)1; Mao, Liu-Liang1; Yang B(杨斌)1; Yang SD(杨尚东)1,2; Yang SD(杨尚东) | |
| 2015 | |
| Source Publication | Chemical Communications
 |
| ISSN | 1359-7345 |
| Volume | 51Issue:19Pages:4101-4104 |
| Abstract | A novel and convenient approach to the synthesis of various phosphorated indolines via a copper-catalyzed radical cascade cyclization reaction has been developed. The reaction employs cheap copper as the catalyst and K2S2O8 as the oxidant under mild conditions. Various alkenes and P-radical precursors are compatible with this transformation. Preliminary mechanistic studies reveal that the addition of the P-radical may initiate the reaction, and then oxidative cyclization may be achieved to afford the desired product. |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1039/c4cc10267c |
| Funding Organization | the NSFC (No. 21272100;21472076);FRFCU (lzujbky-2013-ct02);PCSIRT (IRT1138);Program for New Century Excellent Talents in University (NCET-11-0215;lzujbky-2013-k07) |
| Indexed By | SCI |
| If | 6.567 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/18374 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Yang SD(杨尚东) |
| Affiliation | 1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 2.Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Zhang HY,Mao, Liu-Liang,Yang B,et al. Copper-catalyzed radical cascade cyclization for the synthesis of phosphorated indolines[J]. Chemical Communications,2015,51(19):4101-4104. |
| APA | Zhang HY,Mao, Liu-Liang,Yang B,Yang SD,&杨尚东.(2015).Copper-catalyzed radical cascade cyclization for the synthesis of phosphorated indolines.Chemical Communications,51(19),4101-4104. |
| MLA | Zhang HY,et al."Copper-catalyzed radical cascade cyclization for the synthesis of phosphorated indolines".Chemical Communications 51.19(2015):4101-4104. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| c4cc10267c.pdf（1911KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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