| Metal Bridging for Directing and Accelerating Electron Transfer as Exemplified by Harnessing the Reactivity of AIBN | |
| Department | OSSO国家重点实验室 |
Xie YJ(谢银君); Guo SM(郭生梅); Wu, Longmin; Xia CG(夏春谷) ; Huang HM(黄汉民); Huang HM(黄汉民)
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| 2015 | |
| Source Publication | Angewandte Chemie International Edition
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| ISSN | 1433-7851 |
| Volume | 54Issue:20Pages:5900-5904 |
| Abstract | A new strategy for tuning the electron transfer between radicals and enolates has been developed. This method elicits the innate reactivity of AIBN with a copper catalyst and enables a cascade reaction with cinnamic acids. Electron paramagnetic resonance studies and control experiments indicate that the redox-active copper species not only activates the radical by coordination, but also serves as a bridge to bring the radical and nucleophile within close proximity to facilitate electron transfer. By exploiting possible combinations of redox-active metals and radical entities with suitable coordinating functional groups, this strategy should contribute to the development of a broad range of radical-based reactions. |
| Keyword | Aibn Cinnamic Acids Copper Enolates Single-electron Transfer |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/anie.201411974 |
| Funding Organization | the Chinese Academy of Sciences;the National Natural Science Foundation of China (21222203;21372231;21133011) |
| Indexed By | SCI |
| If | 11.709 |
| Language | 英语 |
| Funding Project | 有机功能材料研究组;均相催化课题组 |
| compositor | 第一作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/18345 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Huang HM(黄汉民) |
| Affiliation | Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Xie YJ,Guo SM,Wu, Longmin,et al. Metal Bridging for Directing and Accelerating Electron Transfer as Exemplified by Harnessing the Reactivity of AIBN[J]. Angewandte Chemie International Edition,2015,54(20):5900-5904. |
| APA | Xie YJ,Guo SM,Wu, Longmin,Xia CG,Huang HM,&黄汉民.(2015).Metal Bridging for Directing and Accelerating Electron Transfer as Exemplified by Harnessing the Reactivity of AIBN.Angewandte Chemie International Edition,54(20),5900-5904. |
| MLA | Xie YJ,et al."Metal Bridging for Directing and Accelerating Electron Transfer as Exemplified by Harnessing the Reactivity of AIBN".Angewandte Chemie International Edition 54.20(2015):5900-5904. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Xie_et_al-2015-Angew（914KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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