| Microwave synthesis of AFI-type aluminophosphate molecular sieve under solvent-free conditions | |
| Department | OSSO国家重点实验室 |
Zhao XH(赵新红)1; Zhao, Jiangbo1; Wen, Juanjuan1; Li A(李安)1; Li GX(李贵贤)1; Wang XL(王晓来)2 ; Zhao XH(赵新红)
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| 2015 | |
| Source Publication | Microporous and Mesoporous Materials
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| ISSN | 1387-1811 |
| Volume | 213Pages:192-196 |
| Abstract | AlPO4-5 aluminophosphate molecular sieve with AFI topology has been successfully synthesized by microwave irradiation under solvent-free conditions. The key influential factors controlling the crystallization of AFI structure were thoroughly investigated. The optimum synthetic conditions of this material are as follows: the initial composition is 1.0Al2O3: 3.0P2O5: 2.0HF: 8.0TEABr(tetraethylammonium bromide): 125C, aluminum isopropoxide is the best aluminum source, and activated carbon needs to be pretreated before used as the reaction medium and hard template. The resultant AlPO4-5 molecular sieves were characterized by X-ray diffraction (XRD), N2 physisorption, scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The results reveal that the obtained samples exhibit hierarchically porous characteristic. |
| Keyword | Alpo4-5 Solvent-free Hierarchical Porous Microwave |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1016/j.micromeso.2015.03.031 |
| Funding Organization | the National Natural Science Foundation of China (Grant No. 21306072;51263012);Development Program of Lanzhou University of Technology for excellent teachers (Grant No. Q201113) |
| Indexed By | SCI |
| If | 3.349 |
| Language | 英语 |
| Funding Project | 多相选择氧化课题组 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/18337 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Zhao XH(赵新红) |
| Affiliation | 1.Lanzhou Univ Technol, Sch Petrochem Engn, Lanzhou 730050, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Oxo Synth & Select Oxidat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Zhao XH,Zhao, Jiangbo,Wen, Juanjuan,et al. Microwave synthesis of AFI-type aluminophosphate molecular sieve under solvent-free conditions[J]. Microporous and Mesoporous Materials,2015,213:192-196. |
| APA | Zhao XH.,Zhao, Jiangbo.,Wen, Juanjuan.,Li A.,Li GX.,...&赵新红.(2015).Microwave synthesis of AFI-type aluminophosphate molecular sieve under solvent-free conditions.Microporous and Mesoporous Materials,213,192-196. |
| MLA | Zhao XH,et al."Microwave synthesis of AFI-type aluminophosphate molecular sieve under solvent-free conditions".Microporous and Mesoporous Materials 213(2015):192-196. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| 2015192-196.pdf（1166KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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