Tribological study of a highly hydrolytically stable phenylboronic acid ester containing benzothiazolyl in mineral oil | |
Department | 固体润滑国家重点实验室 |
Li, Zhipeng1,2; Li, Xiufeng1; Zhang, Yawen1; Ren TH(任天辉)1; Zhao, Yidong3; Zeng, Xiangqiong4; van der Heide, E.4; Ren, Tianhui | |
2014 | |
Source Publication | Applied Surface Science |
ISSN | 0169-4332 |
Volume | 308Pages:91-99 |
Abstract | A novel long chain alkyl phenylboronic acid ester containing heterocyclic compound, bis (1(benzothiazol-2-ylthio) propan-2-yl)-4-dodecylphenylboronic acid ester (DBBMT), was synthesized and characterized. The hydrolytic stability of the DBBMT was evaluated and the results show that DBBMT is of outstanding hydrolytic stability compared with normal borate esters, which indicates that the designed molecular structure, by introducing benzene ring to conjugate with the electron-deficient boron and the benzothiazole as a hinder group, is effective on obtaining a hydrolytically stable long chain alkyl phenylboronic acid ester. The tribological properties of DBBMT and ZDDP in mineral base oil were evaluated using a four-ball tribometer, which suggests that the DBBMT possesses comprehensive tribological properties and could be a potential candidate for the replacement of ZDDP. Furthermore, in order to understand the tribological behaviors, the worn surface was analyzed by X-ray photoelectron spectroscopy (XPS) and X-ray absorption near edge structure (XANES) spectroscopy. The results indicate that the elements S, B, O and Fe perform complicated tribochemical reactions to form the compact tribological film composed of B2O3, FeS, Fe3O4 and FeSO4. |
Keyword | Phenylboronic Acid Ester Heterocyclic Compound Hydrolytic Stability Anti Wear Surface Analysis |
Subject Area | 材料科学与物理化学 |
DOI | 10.1016/j.apsusc.2014.04.116 |
Funding Organization | the National Natural Science Foundation of China (Grant No. 21272157);the Beijing Synchrotron Radiation Facility (Grant No. SR06033);the open projects of the Key State Lab of Solid Lubrication in Lanzhou of China ((Grant No. 1205) |
Indexed By | SCI |
If | 2.711 |
Language | 英语 |
compositor | 第二作者单位 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/18311 |
Collection | 固体润滑国家重点实验室(LSL) |
Corresponding Author | Ren, Tianhui |
Affiliation | 1.Shanghai Jiao Tong Univ, Key Lab Thin Film & Microfabricat, Minist Educ, Sch Chem & Chem Engn, Shanghai 200240, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Lab Solid Lubricat, Lanzhou 730000, Peoples R China 3.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100039, Peoples R China 4.Univ Twente, Lab Surface Technol & Tribol, NL-7522 NB Enschede, Netherlands |
Recommended Citation GB/T 7714 | Li, Zhipeng,Li, Xiufeng,Zhang, Yawen,et al. Tribological study of a highly hydrolytically stable phenylboronic acid ester containing benzothiazolyl in mineral oil[J]. Applied Surface Science,2014,308:91-99. |
APA | Li, Zhipeng.,Li, Xiufeng.,Zhang, Yawen.,Ren TH.,Zhao, Yidong.,...&Ren, Tianhui.(2014).Tribological study of a highly hydrolytically stable phenylboronic acid ester containing benzothiazolyl in mineral oil.Applied Surface Science,308,91-99. |
MLA | Li, Zhipeng,et al."Tribological study of a highly hydrolytically stable phenylboronic acid ester containing benzothiazolyl in mineral oil".Applied Surface Science 308(2014):91-99. |
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LZ01027815.pdf(3041KB) | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text |
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