| The Tribological Chemistry of a Novel Borate Ester Additive and Its Interaction with ZDDP Using XANES and XPS | |
| Department | 固体润滑国家重点实验室 |
| Zhang, Yawen1,2; Zeng, Xiangqiong3; Wu, Hua1; Li, Zhipeng1; Ren TH(任天辉)1; Zhao, Yidong4; Ren TH(任天辉) | |
| 2014 | |
| Source Publication | Tribology Letters
 |
| ISSN | 1023-8883 |
| Volume | 53Issue:3Pages:533-542 |
| Abstract | A novel borate ester containing heterocyclic group, 2,5-bis((2-((6-octadecyl-1,3,6,-dioxazaborocan-2-yl)oxy)propyl)thio)-1,3,4-thiadiazole (BDOT), was prepared and characterized. Its tribological properties and synergistic effect with zinc dialkyl dithiophosphate were evaluated using a four-ball tribometer. The results show that the novel borate additive possesses excellent anti-wear and friction-reducing properties compared with the performance of ZDDP. BDOT combined with ZDDP has a synergistic effect on the tribological properties, especially for the friction-reducing performance. The chemical state of nitrogen, boron and sulfur in thermal films and tribofilms was analyzed by XPS and XANES. XPS analysis suggests that the additive forms a protective film on the rubbing surfaces which is composed of B2O3, BN, FeSO4, FeS2 and Fe2O3. However, the B K-edge XANES shows that no BN was detected in the film. The synergistic effect between BDOT and ZDDP may be due to the formation of right concentration of FeS and FeSO4 in the tribofilm. |
| Keyword | Lubricant Additive Borate Ester Synergistic Effect Xanes |
| Subject Area | 材料科学与物理化学 |
| DOI | 10.1007/s11249-013-0292-x |
| Funding Organization | NSFC No. 21272157;the open projects of the Key State Lab of Solid Lubrication in Lanzhou of China (Grant No. 1205) |
| Indexed By | SCI |
| If | 1.739 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/18309 |
| Collection | 固体润滑国家重点实验室（LSL） |
| Corresponding Author | Ren TH(任天辉) |
| Affiliation | 1.Shanghai Jiao Tong Univ, Minist Educ, Sch Chem & Chem Engn, Key Lab Thin Film & Microfabricat, Shanghai 200240, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China 3.Univ Twente, Lab Surface Technol & Tribol, NL-7500 AE Enschede, Netherlands 4.Chinese Acad Sci, Inst High Energy Phys, Beijing Synchrotron Radiat Facil, Beijing 100039, Peoples R China |
| Recommended Citation GB/T 7714 | Zhang, Yawen,Zeng, Xiangqiong,Wu, Hua,et al. The Tribological Chemistry of a Novel Borate Ester Additive and Its Interaction with ZDDP Using XANES and XPS[J]. Tribology Letters,2014,53(3):533-542. |
| APA | Zhang, Yawen.,Zeng, Xiangqiong.,Wu, Hua.,Li, Zhipeng.,Ren TH.,...&任天辉.(2014).The Tribological Chemistry of a Novel Borate Ester Additive and Its Interaction with ZDDP Using XANES and XPS.Tribology Letters,53(3),533-542. |
| MLA | Zhang, Yawen,et al."The Tribological Chemistry of a Novel Borate Ester Additive and Its Interaction with ZDDP Using XANES and XPS".Tribology Letters 53.3(2014):533-542. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| LZ01027812.pdf（3433KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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