| Nanostructures and Self-Assembly of Organogels via Benzimidazole/Benzothiazole Imide Derivatives with Different Alkyl Substituent Chains | |
| Department | 固体润滑国家重点实验室 |
| Shen, Xihai1,2; Jiao TF(焦体峰)2,3; Zhang, Qingrui2; Guo, Haiying2; Lv, Yaopeng2; Zhou JX(周靖欣)2; Gao FM(高发明)2; Jiao TF(焦体峰) | |
| 2013 | |
| Source Publication | Journal of Nanomaterials
 |
| ISSN | 1687-4110 |
| Abstract | New benzimidazole/benzothiazole imide derivatives with different alkyl substituent chains were designed and synthesized. Their gelation behaviors in 22 solvents were tested as novel low-molecular-mass organic gelators. The test showed that the alkyl substituent chains and headgroups of benzimidazole/benzothiazole residues in gelators played a crucial role in the gelation behavior of all compounds in various organic solvents. More alkyl chains in molecular skeletons in present gelators are favorable for the gelation of organic solvents. SEM and AFM observations revealed that the gelator molecules self-assemble into different aggregates from wrinkle, lamella and belt to dot with change of solvents. Spectral studies indicated that there existed different H-bond formation between imide groups and hydrophobic force of alkyl substituent chains in molecular skeletons. The present work may give some insights into design and character of new organogelators and soft materials with special molecular structures. |
| Subject Area | 材料科学与物理化学 |
| DOI | 10.1155/2013/409087 |
| Funding Organization | the National Natural Science Foundation of China (Grant Nos. 20903078; 21207112);the Natural Science Foundation of Hebei Province (Grant Nos. B2012203060;B2013203108);the China Postdoctoral Science Foundation (Grant Nos. 2011M500540;2012M510770);the Support Program for Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province (Grant No CPRC020);the Science Foundation for the Excellent Youth Scholars from Universities and Colleges of Hebei Province (Grant no. Y2011113);the Scientific Research Foundation for Returned Overseas Chinese Scholars of Hebei Province (Grant no. 2011052);the Open Foundation of State Key Laboratory of Solid Lubrication (Grant No. 1002) |
| Indexed By | SCI |
| If | 1.611 |
| Language | 英语 |
| compositor | 第三作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/18270 |
| Collection | 固体润滑国家重点实验室（LSL） |
| Corresponding Author | Jiao TF(焦体峰) |
| Affiliation | 1.Hebei Normal Univ Sci & Technol, Coll Phys & Chem, Qinhuangdao 066004, Peoples R China 2.Yanshan Univ, Sch Environm & Chem Engn, Hebei Key Lab Appl Chem, Qinhuangdao 066004, Peoples R China 3.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Shen, Xihai,Jiao TF,Zhang, Qingrui,et al. Nanostructures and Self-Assembly of Organogels via Benzimidazole/Benzothiazole Imide Derivatives with Different Alkyl Substituent Chains[J]. Journal of Nanomaterials,2013. |
| APA | Shen, Xihai.,Jiao TF.,Zhang, Qingrui.,Guo, Haiying.,Lv, Yaopeng.,...&焦体峰.(2013).Nanostructures and Self-Assembly of Organogels via Benzimidazole/Benzothiazole Imide Derivatives with Different Alkyl Substituent Chains.Journal of Nanomaterials. |
| MLA | Shen, Xihai,et al."Nanostructures and Self-Assembly of Organogels via Benzimidazole/Benzothiazole Imide Derivatives with Different Alkyl Substituent Chains".Journal of Nanomaterials (2013). |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| LZ01027763.pdf（11968KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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