| Self-Assembly, Interfacial Nanostructure, and Supramolecular Chirality of the Langmuir-Blodgett Films of Some Schiff Base Derivatives without Alkyl Chain | |
| Department | 固体润滑国家重点实验室 |
| Jiao TF(焦体峰)1,2; Xing, Ruirui1; Zhang, Qingrui1; Lv, Yaopeng1; Zhou JX(周靖欣)1; Gao FM(高发明)1; Jiao TF(焦体峰) | |
| 2013 | |
| Source Publication | Journal of Nanomaterials
 |
| ISSN | 1687-4110 |
| Abstract | A special naphthyl-containing Schiff base derivative, N,N-bis(2-hydroxy-1-naphthylidene)-1,2-phenylenediamine, was synthesized, and its coordination with various metal ions in situ at the air/water interface has been investigated. Although the ligand contains no alkyl chain, it can be spread on water surface. When metal ions existed in the subphase, an interfacial coordination between the ligand and different metal ions occurred in the spreading film, while different Nanostructures were fabricated in the monolayers. Interestingly to note that among various metal ions, only the in situ coordination-induced Cu(II)-complex film showed supramolecular chirality, although themultilayer films from the ligand or preformed complex are achiral. The chirality of the in situ Cu(II)-coordinated Langmuir film was developed due to the special distorted coordination reaction and the spatial limitation at the air/water interface. A possible organization mechanism at the air/water interface was suggested. |
| Subject Area | 材料科学与物理化学 |
| DOI | 10.1155/2013/297564 |
| Funding Organization | the National Natural Science Foundation of China (Grant Nos. 20903078; 21207112);the Natural Science Foundation of Hebei Province (Grant Nos. B2012203060;B2013203108);the China Postdoctoral Science Foundation (Grant Nos. 2011M500540;2012M510770);the Support Program for Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province (Grant No CPRC020);the Science Foundation for the Excellent Youth Scholars from Universities and Colleges of Hebei Province (Grant no. Y2011113);the Scientific Research Foundation for Returned Overseas Chinese Scholars of Hebei Province (Grant no. 2011052);the Open Foundation of State Key Laboratory of Solid Lubrication (Grant No. 1002) |
| Indexed By | SCI |
| If | 1.611 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/18258 |
| Collection | 固体润滑国家重点实验室（LSL） |
| Corresponding Author | Zhang, Qingrui; Jiao TF(焦体峰) |
| Affiliation | 1.Yanshan Univ, Sch Environm & Chem Engn, Hebei Key Lab Appl Chem, Qinhuangdao 066004, Hebei, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Gansu, Peoples R China |
| Recommended Citation GB/T 7714 | Jiao TF,Xing, Ruirui,Zhang, Qingrui,et al. Self-Assembly, Interfacial Nanostructure, and Supramolecular Chirality of the Langmuir-Blodgett Films of Some Schiff Base Derivatives without Alkyl Chain[J]. Journal of Nanomaterials,2013. |
| APA | Jiao TF.,Xing, Ruirui.,Zhang, Qingrui.,Lv, Yaopeng.,Zhou JX.,...&焦体峰.(2013).Self-Assembly, Interfacial Nanostructure, and Supramolecular Chirality of the Langmuir-Blodgett Films of Some Schiff Base Derivatives without Alkyl Chain.Journal of Nanomaterials. |
| MLA | Jiao TF,et al."Self-Assembly, Interfacial Nanostructure, and Supramolecular Chirality of the Langmuir-Blodgett Films of Some Schiff Base Derivatives without Alkyl Chain".Journal of Nanomaterials (2013). |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| LZ01027746.pdf（3017KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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