| Synthesis of Aryl Thiocyanates via Copper-Catalyzed Aerobic Oxidative Cross-Coupling between Arylboronic Acids and KSCN | |
| Department | OSSO国家重点实验室 |
| Sun N(孙楠)1; Zhang, Han1; Mo WM(莫卫民)1; Hu BX(胡宝祥)1; Shen ZL(沈振陆)1; Hu XQ(胡信全)1,2; Hu XQ(胡信全) | |
| 2013 | |
| Source Publication | SYNLETT
 |
| ISSN | 0936-5214 |
| Volume | 24Issue:11Pages:1443-1447 |
| Abstract | A new protocol for the preparation of aryl thiocyanates by the cross-coupling reaction of arylboronic acids with KSCN salt is described. The coupling reaction was catalyzed by 20 mol% of copper acetate in the presence of 2.0 equivalents 4-methylpyridine serving both as ligand and base under 0.2 MPa of molecular oxygen. A variety of arylboronic acids, including those with substituents at ortho position, were suitable under the reaction conditions. |
| Keyword | Aryl Thiocyanates Arylboronic Acids Potassium Thiocyanate Copper Acetate Oxidative Cross-coupling Reaction |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1055/s-0033-1338939 |
| Funding Organization | the Major Project of Science and Technology Department of Zhejiang Province (No. 2010C11039);the Key Innovative Team Project of Zhejiang Province, China (No. 2009R50002) |
| Indexed By | SCI |
| If | 2.463 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/18246 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Hu XQ(胡信全) |
| Affiliation | 1.Zhejiang Univ Technol, Coll Chem Engn & Mat Sci, Hangzhou 310014, Zhejiang, Peoples R China 2.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Sun N,Zhang, Han,Mo WM,et al. Synthesis of Aryl Thiocyanates via Copper-Catalyzed Aerobic Oxidative Cross-Coupling between Arylboronic Acids and KSCN[J]. SYNLETT,2013,24(11):1443-1447. |
| APA | Sun N.,Zhang, Han.,Mo WM.,Hu BX.,Shen ZL.,...&胡信全.(2013).Synthesis of Aryl Thiocyanates via Copper-Catalyzed Aerobic Oxidative Cross-Coupling between Arylboronic Acids and KSCN.SYNLETT,24(11),1443-1447. |
| MLA | Sun N,et al."Synthesis of Aryl Thiocyanates via Copper-Catalyzed Aerobic Oxidative Cross-Coupling between Arylboronic Acids and KSCN".SYNLETT 24.11(2013):1443-1447. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| SYNLETT 2013 Vol.24,（190KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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