| Self-assembly of organogels via new luminol imide derivatives: diverse nanostructures and substituent chain effect | |
| Department | 固体润滑国家重点实验室 |
| Jiao TF(焦体峰)1,2; Huang, Qinqin1; Zhang, Qingrui1; Xiao, Debao1; Zhou JX(周靖欣)1; Gao FM(高发明)1; Jiao TF(焦体峰) | |
| 2013 | |
| Source Publication | Nanoscale Research Letters
 |
| ISSN | 1556-276X |
| Volume | 8 |
| Abstract | Luminol is considered as an efficient sycpstem in electrochemiluminescence (ECL) measurements for the detection of hydrogen peroxide. In this paper, new luminol imide derivatives with different alkyl substituent chains were designed and synthesized. Their gelation behaviors in 26 solvents were tested as novel low molecular mass organic gelators. It was shown that the length and number of alkyl substituent chains linked to a benzene ring in gelators played a crucial role in the gelation behavior of all compounds in various organic solvents. Longer alkyl chains in molecular skeletons in present gelators are favorable for the gelation of organic solvents. Scanning electron microscope and atomic force microscope observations revealed that the gelator molecules self-assemble into different micro/nanoscale aggregates from a dot, flower, belt, rod, and lamella to wrinkle with change of solvents. Spectral studies indicated that there existed different H-bond formations and hydrophobic forces, depending on the alkyl substituent chains in molecular skeletons. The present work may give some insight to the design and characteristic of new versatile soft materials and potential ECL biosensors with special molecular structures. |
| Keyword | Nanostructure Self-assembly Organogel Luminol Derivative Substituent Group Effect |
| Subject Area | 材料科学与物理化学 |
| DOI | 10.1186/1556-276X-8-278 |
| Funding Organization | the National Natural Science Foundation of China (Grant Nos. 20903078;21073154;21207112);the Natural Science Foundation of Hebei Province (Grant Nos. B2012203060;B2013203108);the China Postdoctoral Science Foundation (Grant Nos. 2011M500540;2012M510770);the Support Program for Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province (Grant No CPRC020);the Science Foundation for the Excellent Youth Scholars from Universities and Colleges of Hebei Province (Grant no. Y2011113);the Scientific Research Foundation for Returned Overseas Chinese Scholars of Hebei Province (Grant no. 2011052);the Open Foundation of State Key Laboratory of Solid Lubrication (Grant No. 1002) |
| Indexed By | SCI |
| If | 2.481 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/18236 |
| Collection | 固体润滑国家重点实验室（LSL） |
| Corresponding Author | Jiao TF(焦体峰) |
| Affiliation | 1.Yanshan Univ, Sch Environm & Chem Engn, Hebei Key Lab Appl Chem, Qinhuangdao 066004, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Jiao TF,Huang, Qinqin,Zhang, Qingrui,et al. Self-assembly of organogels via new luminol imide derivatives: diverse nanostructures and substituent chain effect[J]. Nanoscale Research Letters,2013,8. |
| APA | Jiao TF.,Huang, Qinqin.,Zhang, Qingrui.,Xiao, Debao.,Zhou JX.,...&焦体峰.(2013).Self-assembly of organogels via new luminol imide derivatives: diverse nanostructures and substituent chain effect.Nanoscale Research Letters,8. |
| MLA | Jiao TF,et al."Self-assembly of organogels via new luminol imide derivatives: diverse nanostructures and substituent chain effect".Nanoscale Research Letters 8(2013). |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| LZ01027712.pdf（694KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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