| Palladium-Catalyzed Insertion of N-tosylhydrazones and Trapping with Carbon Nucleophiles | |
| Department | 固体润滑国家重点实验室 |
| Zhou, Ping-Xin1; Ye, Yu-Ying1; Liang YM(梁永民)1,2; Liang YM(梁永民) | |
| 2013 | |
| Source Publication | Organic Letters
 |
| ISSN | 1523-7060 |
| Volume | 15Issue:19Pages:5080-5083 |
| Abstract | A Pd-catalyzed three-component cross-coupling reaction of vinyl iodide, N-tosylhydrazone, and carbon nucleophiles is reported, and a one-pot procedure is also developed. The cross-coupling is proposed to proceed through a palladium-carbene migratory Insertion, carbopalladation other than classic palladium-carbene migratory insertion, and beta-H elimination. Moreover, the reaction proceeds under mild conditions and with high stereoselectivity. |
| Subject Area | 材料科学与物理化学 |
| DOI | 10.1021/ol402457h |
| Funding Organization | the National Science Foundation (NSF 21072080;21272101);the National Basic Research Program of China (973 Program) 2010CB8-33203;the “111” Program of MOE and PCSIRT : IRT1138 |
| Indexed By | SCI |
| If | 6.324 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/18210 |
| Collection | 固体润滑国家重点实验室（LSL） |
| Corresponding Author | Liang YM(梁永民) |
| Affiliation | 1.Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China 2.Chinese Acad Sci, Lanzhou Inst Chem Phys, State Key Lab Solid Lubricat, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Zhou, Ping-Xin,Ye, Yu-Ying,Liang YM,et al. Palladium-Catalyzed Insertion of N-tosylhydrazones and Trapping with Carbon Nucleophiles[J]. Organic Letters,2013,15(19):5080-5083. |
| APA | Zhou, Ping-Xin,Ye, Yu-Ying,Liang YM,&梁永民.(2013).Palladium-Catalyzed Insertion of N-tosylhydrazones and Trapping with Carbon Nucleophiles.Organic Letters,15(19),5080-5083. |
| MLA | Zhou, Ping-Xin,et al."Palladium-Catalyzed Insertion of N-tosylhydrazones and Trapping with Carbon Nucleophiles".Organic Letters 15.19(2013):5080-5083. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| Org. Lett., 2013, 15（277KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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