| Interfacial assembly of a series of Cu(II)-coordinated Schiff bases complexes: Orderly nanostructures and supramolecular chirality | |
| Department | 固体润滑国家重点实验室 |
| Jiao TF(焦体峰)1,2; Li XuHui1; Zhang QingRui1; Li QiuRong1; Zhou JX(周靖欣)1; Gao FM(高发明)1; Jiao TF(焦体峰) | |
| 2013 | |
| Source Publication | SCIENCE CHINA Technological Sciences
 |
| ISSN | 1674-7321 |
| Volume | 56Issue:1Pages:20-24 |
| Abstract | Four achiral Cu(II)-coordinated Schiff bases complexes containing aromatic structures were synthesized and their supramolecular assemblies at the air/water interface were investigated. All the compounds could be spread on water surface although they have no alkyl chains. The Schiff base complex molecules with naphthyl groups tended to form J-aggregate in the Langmuir-Blodgett (LB) films transferred from water surface. By investigation of atomic force microscopy, a multilayer film or three-dimensional structures were observed. It was interesting to note that the LB films of achiral compound Cu-NA with naphthyl segment and without methyl groups transferred from water surface showed chirality. The supramolecular chirality in the present LB films was suggested to be due to a cooperative stereoregular pi-pi stacking of the functional groups in a helical sense. This research work provides a helpful clue for regulating the nanostructures and supramolecular chiral assembly in organized films. |
| Keyword | Interfacial Assembly Langmuir-blodgett Film Supramolecular Chirality Schiff Base |
| Subject Area | 材料科学与物理化学 |
| DOI | 10.1007/s11431-012-5062-8 |
| Funding Organization | the National Natural Science Foundation of China (Grant Nos. 20903078;21207112);the Natural Science Foundation of Hebei Province (Grant No. B2012203060);the China Postdoctoral Science Foundation (Grant Nos. 2011M500540;2012M510770);the Support Program for Hundred Excellent Innovation Talents from Universities and Colleges of Hebei Province (Grant No. CPRC020);the Science Foundation for the Excellent Youth Scholars from Universities and Colleges of Hebei Province (Grant No. Y2011113);the Scientific Research Foundation for Returned Overseas Chinese Scholars of Hebei Province (Grant No. 2011052);the Open Foundation of State Key Laboratory of Solid Lubrication (Grant No. 1002) |
| Indexed By | SCI |
| If | 1.113 |
| Language | 英语 |
| compositor | 第二作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/18175 |
| Collection | 固体润滑国家重点实验室（LSL） |
| Corresponding Author | Jiao TF(焦体峰) |
| Affiliation | 1.Yanshan Univ, Hebei Key Lab Appl Chem, Sch Environm & Chem Engn, Qinhuangdao 066004, Peoples R China 2.Chinese Acad Sci, State Key Lab Solid Lubricat, Lanzhou Inst Chem Phys, Lanzhou 730000, Peoples R China |
| Recommended Citation GB/T 7714 | Jiao TF,Li XuHui,Zhang QingRui,et al. Interfacial assembly of a series of Cu(II)-coordinated Schiff bases complexes: Orderly nanostructures and supramolecular chirality[J]. SCIENCE CHINA Technological Sciences,2013,56(1):20-24. |
| APA | Jiao TF.,Li XuHui.,Zhang QingRui.,Li QiuRong.,Zhou JX.,...&焦体峰.(2013).Interfacial assembly of a series of Cu(II)-coordinated Schiff bases complexes: Orderly nanostructures and supramolecular chirality.SCIENCE CHINA Technological Sciences,56(1),20-24. |
| MLA | Jiao TF,et al."Interfacial assembly of a series of Cu(II)-coordinated Schiff bases complexes: Orderly nanostructures and supramolecular chirality".SCIENCE CHINA Technological Sciences 56.1(2013):20-24. |
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| File Name/Size | DocType | Version | Access | License | ||
| Interfacialassem_省略_（811KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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