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Development of a superporous hydroxyethyl cellulose-based hydrogel by anionic surfactant micelle templating with fast swelling and superabsorbent properties
Department环境材料与生态化学研究发展中心
Shi XN(施小宁)1,2; Tang J(唐洁)2; Wang AQ(王爱勤)2; Shi XN(施小宁)
2015
Source PublicationJournal of Applied Polymer Science
ISSN0021-8995
Volume132Issue:23Pages:42027(1-8)
AbstractThe self-assembling anionic surfactant, sodium n-dodecyl sulfonate (SDS) micelles were used as pore-forming templating for fabricating novel superporous hydroxyethyl cellulose-grafting-poly(sodium acrylate)/attapulgite (HEC-g-PNaA/APT) hydrogels. The network characteristics, morphologies of the hydrogels and removing of SDS micelles from the final product by washing with ethanol/water (v/v, 7 : 3) procedure were determined by Fourier transform infrared spectroscopy and scanning electron microscopy, as well as by determination of swelling ratio, swelling rate, and stimuli response to salts and pHs. The results showed that the added-SDS concentration significantly affected the morphologies and pore structure of the hydrogel, and 2 mM SDS facilitates to form a homogeneous and well-defined pore structure in the gel network to extremely improve the swelling ratio and swelling rate. The 2 mM SDS-added superporous HEC-based hydrogel not only had highest equilibrium swelling ratio (Qeq, 1118, 102 g g−1 in distilled water and 0.9 wt % NaCl solution), rapid swelling rate (kis, 5.2840 g g s−1), also showed multistimulus responses to salts and pHs, which may allow its applications in several areas such as adsorption, separation and biomedical materials. 
KeywordPorous Materials Self-assembly Stimuli-sensitive Polymers Surfactants Swelling
Subject Area环境材料与生态化学
DOI10.1002/app.42027
Funding Organizationthe Youth Fund Project of Gansu University of Traditional Chinese Medicine (2305016601);the Science and Technology Support Project of Jiangsu Provincial Sci. & Tech. Department (No. BY2010012);the National Natural Science Foundation of China (No. 21377135)
Indexed BySCI
If1.866
Language英语
Funding Project功能复合材料组
compositor第二作者单位
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Cited Times:18[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/18127
Collection环境材料与生态化学研究发展中心
Corresponding AuthorShi XN(施小宁)
Affiliation1.Gansu Univ Tradit Chinese Med, Dept Appl Chem, Lanzhou 730000, Peoples R China
2.Chinese Acad Sci, Lanzhou Inst Chem Phys, Ctr Ecomat & Green Chem, Lanzhou 730000, Peoples R China
Recommended Citation
GB/T 7714
Shi XN,Tang J,Wang AQ,et al. Development of a superporous hydroxyethyl cellulose-based hydrogel by anionic surfactant micelle templating with fast swelling and superabsorbent properties[J]. Journal of Applied Polymer Science,2015,132(23):42027(1-8).
APA Shi XN,Tang J,Wang AQ,&施小宁.(2015).Development of a superporous hydroxyethyl cellulose-based hydrogel by anionic surfactant micelle templating with fast swelling and superabsorbent properties.Journal of Applied Polymer Science,132(23),42027(1-8).
MLA Shi XN,et al."Development of a superporous hydroxyethyl cellulose-based hydrogel by anionic surfactant micelle templating with fast swelling and superabsorbent properties".Journal of Applied Polymer Science 132.23(2015):42027(1-8).
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