| ESR studies on a Friedel-Crafts alkylation reaction in [bmim]Cl-AlCl3 ionic liquid | |
| Department | 甘肃省天然药物重点实验室 ; 固体润滑国家重点实验室 |
Zhai CP(翟翠萍); Song AX(宋爱新); Liu WM(刘维民) ; Wang HQ(汪汉卿)
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| 2006 | |
| Source Publication | Journal of the Chinese Chemical Society
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| ISSN | 0009-4536 |
| Volume | 53Issue:4Pages:887-890 |
| Abstract | The paramagnetic complexes formed in Friedel-Crafts alkylation reaction systems are invistigated by electron spin resonance (ESR) spectroscopy, in room temperature ionic liquids system 1-butyl-3-methyllimidazolium chloride-aluminium chloride ([bmim]Cl-AlCl3). The results indicate that ESR spectra observed are due to polycyclic aromatic radical cations formed from their parent hydrocarbons. ESR spectrum of spin adduct is obtained in an ionic liquid system composed of [bmim]Cl-AlCl3. In acidic solution the 14N hyperfine coupling constant of 4-oxo-TEMPO, 2.15 mT, is appreciably larger due to an adduct formed with AlCl3. |
| Keyword | Esr Cation Radical Ionic Liquids Friedel-crafts Alkylation |
| Subject Area | 分析化学与药物化学 |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | 药物化学成分研究组 ; 空间润滑材料组 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/1465 |
| Collection | 中科院西北特色植物资源化学重点实验室/甘肃省天然药物重点实验室 固体润滑国家重点实验室（LSL） |
| Corresponding Author | Wang HQ(汪汉卿) |
| Recommended Citation GB/T 7714 | Zhai CP,Song AX,Liu WM,et al. ESR studies on a Friedel-Crafts alkylation reaction in [bmim]Cl-AlCl3 ionic liquid[J]. Journal of the Chinese Chemical Society,2006,53(4):887-890. |
| APA | 翟翠萍,宋爱新,刘维民,&汪汉卿.(2006).ESR studies on a Friedel-Crafts alkylation reaction in [bmim]Cl-AlCl3 ionic liquid.Journal of the Chinese Chemical Society,53(4),887-890. |
| MLA | 翟翠萍,et al."ESR studies on a Friedel-Crafts alkylation reaction in [bmim]Cl-AlCl3 ionic liquid".Journal of the Chinese Chemical Society 53.4(2006):887-890. |
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| Esr studies on a fri（591KB） | 开放获取 | License | View Application Full Text | |||
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