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Superabsorbent composite XXII. Effects of modified sepiolite on water absorbency and swelling behavior of chitosan-g-poly (acrylic acid)/sepiolite superabsorbent composite
Department环境材料与生态化学研究发展中心
Xie YT(谢云涛); Wang AQ(王爱勤); Liu G(刘刚); 王爱勤 aqwang@licp.cas.cn
2010
Source PublicationPolymer Composites
ISSN0272-8397
Volume31Issue:1Pages:89-96
AbstractIn this work, a series of chitosan-g-poly(acrylic acid)/sepiolite (CTS-g-PAA/ST) superabsorbent composites containing raw sepiolite, acid-activated sepiolite, and cation-exchanged sepiolite were synthesized by free radical graft polymerization in aqueous solution, using N,N0-methylenebisacrylamide as a crosslinker and ammonium persulfate as an initiator. The effects of raw sepiolite, acid-activated sepiolite, and cation exchanged sepoilite on equilibrium water absorbency, swelling rate, and swelling behavior in different pH value solution of superabsorbent composites were systematically investigated. The results from FTIR spectra showed that chitosan and sepiolite participated in graft polymerization reaction with acrylic acid. The introduction of acid-activated and cation-exchanged sepiolite into chitosan-g-poly(acrylic acid) polymeric network could improve water absorbency and swelling rate compared with that of the raw sepiolite. All prepared samples have similar swelling behavior in different pH solutions and the equilibrium water absorbencies of samples keep roughly constant in the pH range from 4 to 12.
Subject Area功能高分子
Funding Organization中科院西部行动项目(KGCX2-YW-501)
Indexed BySCI
Language英语
Funding Project功能复合材料组
Document Type期刊论文
Identifierhttp://ir.licp.cn/handle/362003/131
Collection环境材料与生态化学研究发展中心
Corresponding Author王爱勤 aqwang@licp.cas.cn
Recommended Citation
GB/T 7714
Xie YT,Wang AQ,Liu G,et al. Superabsorbent composite XXII. Effects of modified sepiolite on water absorbency and swelling behavior of chitosan-g-poly (acrylic acid)/sepiolite superabsorbent composite[J]. Polymer Composites,2010,31(1):89-96.
APA 谢云涛,王爱勤,刘刚,&王爱勤 aqwang@licp.cas.cn.(2010).Superabsorbent composite XXII. Effects of modified sepiolite on water absorbency and swelling behavior of chitosan-g-poly (acrylic acid)/sepiolite superabsorbent composite.Polymer Composites,31(1),89-96.
MLA 谢云涛,et al."Superabsorbent composite XXII. Effects of modified sepiolite on water absorbency and swelling behavior of chitosan-g-poly (acrylic acid)/sepiolite superabsorbent composite".Polymer Composites 31.1(2010):89-96.
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