Synthesis, characterization and swelling behaviors of hydroxyethyl cellulose-g-poly(acrylic acid)/attapulgite superabsorbent composite | |
Department | 环境材料与生态化学研究发展中心 |
Wang JL(王金磊); Wang WB(王文波); Wang AQ(王爱勤); 王爱勤 aqwang@licp.cas.cn | |
2010 | |
Source Publication | Polymer Engineering and Science |
ISSN | 0032-3888 |
Volume | 50Issue:5Pages:1019-1027 |
Abstract | In this work, a series of novel hydroxyethyl cellulose-g-poly(acrylic acid)/attapulgite (HEC-g-PAA/APT) superabsorbent composites were prepared through the graft polymerization of hydroxyethyl cellulose (HEC), partially neutralized acrylic acid (AA), and attapulgite (APT) in aqueous solution, and the composites were characterized by means of Fourier-transform spectroscopy, scanning electron microscopy, and transmission electron microscopy. The effects of polymerization variables including concentrations of the initiator and crosslinker and APT content on water absorbency were studied, and the swelling properties in various pH solutions as well as the swelling kinetics in various saline solutions were also systematically evaluated. Results showed that the introduction of 5 wt% APT into HEC-g-PAA polymeric network could improve both water absorbency and water absorption rate of the superabsorbent composites. In addition, the superabsorbent composites retained high water absorbency over a wide pH range of 4–10, and the swelling kinetics of the superabsorbent composites in CaCl2 and FeCl3 solutions exhibited a remarkable overshooting phenomenon. |
Subject Area | 功能高分子 |
Funding Organization | 中科院西部行动项目(KGCX2-YW-501) |
Indexed By | SCI |
Language | 英语 |
Funding Project | 功能复合材料组 |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.licp.cn/handle/362003/127 |
Collection | 环境材料与生态化学研究发展中心 |
Corresponding Author | 王爱勤 aqwang@licp.cas.cn |
Recommended Citation GB/T 7714 | Wang JL,Wang WB,Wang AQ,et al. Synthesis, characterization and swelling behaviors of hydroxyethyl cellulose-g-poly(acrylic acid)/attapulgite superabsorbent composite[J]. Polymer Engineering and Science,2010,50(5):1019-1027. |
APA | 王金磊,王文波,王爱勤,&王爱勤 aqwang@licp.cas.cn.(2010).Synthesis, characterization and swelling behaviors of hydroxyethyl cellulose-g-poly(acrylic acid)/attapulgite superabsorbent composite.Polymer Engineering and Science,50(5),1019-1027. |
MLA | 王金磊,et al."Synthesis, characterization and swelling behaviors of hydroxyethyl cellulose-g-poly(acrylic acid)/attapulgite superabsorbent composite".Polymer Engineering and Science 50.5(2010):1019-1027. |
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