| Nitrogen Dioxide-Catalyzed Electrophilic Iodination of Arenes | |
| Department | OSSO国家重点实验室 |
Ren, Yun-Lai1; Shang, Huantao1; Wang, Jianji1,2; Tian, Xinzhe1; Zhao, Shuang1; Wang, Qian1; Li FW(李福伟)3 ; Jianji Wang
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| 2013 | |
| Source Publication | Advanced Synthesis and Catalysis
 |
| ISSN | 1615-4150 |
| Volume | 355Issue:17Pages:3437-3442 |
| Abstract | Nitrogen dioxide is demonstrated to be an effective catalyst precursor for the iodination of alkoxy-substituted benzenes and naphthalenes. Different from the transition metal catalysts, nitrogen dioxide can be easily separated from the final products, and is free of heavy metal waste. Although the present catalyst precursor is toxic, it does not stain the final products due to its low-boiling character. No other reagents apart from 0.5equiv. of iodine (I-2), 6.5mol% nitrogen dioxide and acetonitrile solvent were used in the iodination, and basically all the iodine atoms in the iodine source were transferred to the iodination products, showing that the presented protocol is highly atom-economic and practical. |
| Keyword | Arenes Catalysis Iodination Nitrogen Dioxide |
| Subject Area | 物理化学与绿色催化 |
| DOI | 10.1002/adsc.201300581 |
| Funding Organization | the National Natural Science Foundation of China (Grant No. 21002023);the National Basic Research Program of China (975 Program, Grant No. 2011CB211702) |
| Indexed By | SCI |
| If | 5.542 |
| Language | 英语 |
| Funding Project | 均相催化课题组 |
| compositor | 第三作者单位 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.licp.cn/handle/362003/12390 |
| Collection | 羰基合成与选择氧化国家重点实验室（OSSO） |
| Corresponding Author | Jianji Wang |
| Affiliation | 1.Henan Univ Sci & Technol, Sch Chem Engn & Pharmaceut, Luoyang 471003, Henan, Peoples R China 2.Henan Normal Univ, Sch Chem & Chem Engn, Key Lab Green Chem Media & React, Minist Educ, Xinxiang 453007, Henan, Peoples R China 3.Chinese Acad Sci, State Key Lab Oxo Synth & Select Oxidat, Lanzhou Inst Chem Phys, Lanzhou 730000, Gansu, Peoples R China |
| Recommended Citation GB/T 7714 | Ren, Yun-Lai,Shang, Huantao,Wang, Jianji,et al. Nitrogen Dioxide-Catalyzed Electrophilic Iodination of Arenes[J]. Advanced Synthesis and Catalysis,2013,355(17):3437-3442. |
| APA | Ren, Yun-Lai.,Shang, Huantao.,Wang, Jianji.,Tian, Xinzhe.,Zhao, Shuang.,...&Jianji Wang.(2013).Nitrogen Dioxide-Catalyzed Electrophilic Iodination of Arenes.Advanced Synthesis and Catalysis,355(17),3437-3442. |
| MLA | Ren, Yun-Lai,et al."Nitrogen Dioxide-Catalyzed Electrophilic Iodination of Arenes".Advanced Synthesis and Catalysis 355.17(2013):3437-3442. |
| Files in This Item: | ||||||
| File Name/Size | DocType | Version | Access | License | ||
| LZ01027435.pdf（199KB） | 期刊论文 | 作者接受稿 | 开放获取 | CC BY-NC-SA | View Application Full Text | |
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